Hi David
The two main problems with the brake shoes skewing are the springs on the shoes are incorrectly fitted or the beehive retention springs are left off or not located properly.
The Manumatic master cylinder is identical to the manual master cylinder the only differences are the clutch bore needs to be opened out and then honed to size and the hydraulic outlet threads need to be drilled and tapped.
These cylinders are really cheap to buy as there is no call for them, I purchased 2 for £15 last year, and it cost me £100 to get them machined, a real find, seen a few on ebay and at autojumbles
The trouble with making changes to the rear bias is the rear brakes are normally lightly loaded and will lock up quicker or not work at all, you could run out of of brake fluid in the worst case before the bakes work, depending whether the slave is larger or smaller, in your case it will be larger so the pedal will need to travel further to get the braking effect.
You probably know all this.
Best Trevor